A Meta-Analysis on the Effects of Modified Biochar Preparation and Structural Regulation on the Remediation of Soils Contaminated by Heavy Metals and Other Pollutants

Authors

  • Haotong Li
  • Yu Gao
  • Guoqing Li
  • Junchao Chen
  • Jinlan Ji

DOI:

https://doi.org/10.62051/ijnres.v8n7.01

Keywords:

Biochar, Heavy Metals, Modification, Adsorption, Soil Remediation.

Abstract

To investigate the effects of biochar preparation and structural regulation on the remediation of heavy-metal-contaminated soils in China, this study used a Meta-analysis method to systematically collect and integrate published literature worldwide including field experiments, pot experiments, and laboratory incubation studies. We quantitatively evaluated the influences of straw-derived biochar properties such as feedstock type, pyrolysis temperature, modification method, and application rate on soil physicochemical properties and the remediation efficiency for soils contaminated with lead (Pb), cadmium (Cd), and arsenic (As).The results showed that modified biochar significantly improved soil physicochemical properties. Compared with the control group, the average increases in soil pH, soil organic carbon (SOC) content, and cation exchange capacity (CEC) reached 10.34%, 36.48%, and 23.42%, respectively. Among different modification methods, thiourea modification had the most obvious effect on increasing soil pH (25.83%), microbial modification most prominently promoted SOC (61.25%), and Mn modification increased CEC by up to 132.69%.In terms of biochar intrinsic properties, biochar with pH 9–10 achieved the highest SOC improvement (46.38%); pyrolysis temperature above 700°C performed best in enhancing pH and CEC (21.08% and 74.56%, respectively); application rate of 1%–2% led to the largest CEC increase (55.72%), while 2%–5% most effectively improved SOC (35.18%). For soil conditions, modified biochar increased CEC most significantly in alkaline soils (48.08%), and the improvement in sandy soils was markedly higher than in other soil textures. For heavy metal remediation, the immobilization of Pb by modified biochar was dominated by pH and ash content, with the best performance at high temperature (>700°C) and application rate of 4%–6%. The optimal conditions for Cd remediation were lignocellulosic feedstock, organic modification, and 2%–3% application rate, which reduced soil available Cd and plant Cd content by 65.01% and 70.72%, respectively. For As remediation, high-temperature pyrolysis (>450°C) combined with Fe/Mn modification and an application rate of 0.5%–2% showed the most significant effects. Split application maintained soil pH more effectively than a single basal application.

References

[1] Fan, J. J. (2019). Preparation of thiol-modified biochar and its application in remediation of heavy metal-contaminated soil [Master’s thesis]. Huaqiao University.

[2] Jiang, S. X., & Qian, H. M. (2026). Monitoring and remediation measures for heavy metal contamination in farmland soil. Agricultural Development & Equipment, (03), 85–87.

[3] Ministry of Ecology and Environment of the People’s Republic of China. (2022). China ecological environment status bulletin 2021 (excerpt). Environmental Protection, 50(12), 61–74. https://doi.org/10.14026/j.cnki.0253-9705.2022.12.009

[4] Ding, H. Y. (2014). Environmental adsorption behavior of biochar and its application in remediation of soil contaminated by heavy metal cadmium [Doctoral dissertation]. Xiamen University.

[5] Xu, Q. B. (2021). Effect of straw-derived biochar on enhancing phytoremediation of lead-contaminated soil by Portulaca oleracea L. [Master’s thesis]. Northeast Agricultural University. https://doi.org/10.27010/d.cnki.gdbnu.2021.000959

[6] Wu, M. Y. (2025). Remediation of cadmium and arsenic contaminated soil using biochar zeolite supported nanoscale zero valent iron [Master’s thesis]. Northwest A&F University. https://doi.org/10.27409/d.cnki.gxbnu.2025.002751

[7] Wang, T. (2013). Remediation of heavy metal-contaminated soil using combined highly efficient mutagenic bacteria and biochar [Doctoral dissertation]. Nankai University.

[8] Gao, C. Q. (2018). Adsorption of lead by biochar and its modified materials [Master’s thesis]. Chang’an University.

[9] Fei, Q. O., Jia, Y. J., Liu, S. D., et al. (2024). Research progress on iron tailings resource utilization and soil remediation technology in iron mining areas. Chemical Minerals and Processing, 53(07), 37–46. https://doi.org/10.16283/j.cnki.hgkwyjg.2024.07.006

[10] Fan, T., Ye, W. L., Chen, H. Y., et al. (2013). Research on heavy metal contamination status and remediation technologies of farmland soil. Journal of Ecology and Environment, 22(10), 1727–1736. https://doi.org/10.16283/j.cnki.1674-5906.2013.10.016

[11] Zhang, W. M., Xiu, L. Q., Wu, D., et al. (2021). Structure and physicochemical properties of biochar: Retrospect and prospect. Acta Agronomica Sinica, 47(01), 1–18.

[12] Chen, W. F., Zhang, W. M., Meng, J., et al. (2011). Research on biochar application technology. Engineering Sciences, 13(02), 83–89.

[13] Yuan, Y. W., Tian, Y. S., Zhao, L. X., et al. (2012). Research progress on application of biochar. Renewable Energy Resources, 30(09), 45–49. https://doi.org/10.13941/j.cnki.21-1469/tk.2012.09.018

[14] Inyang, M. I., Gao, B., Yao, Y., Xue, Y., Zimmerman, A., Mosa, A., … Cao, X. (2016). A review of biochar as a low-cost adsorbent for aqueous heavy metal removal. Critical Reviews in Environmental Science and Technology, 46(4), 406–433. https://doi.org/10.1080/10643389.2015.1096880

[15] Li, J. R., Xu, Y. M., Lin, D. S., et al. (2014). Research progress on in-situ immobilization remediation of heavy metal contamination in farmland. Journal of Ecology and Environment, 23(04), 721–728. https://doi.org/10.16258/j.cnki.1674-5906.2014.04.013

[16] Xu, C., Lin, X. B., Wu, Q. T., et al. (2012). Effects of biochar on heavy metal availability and nutrient content in contaminated soil under flooding conditions. Journal of Soil and Water Conservation, 26(06), 194–198. https://doi.org/10.13870/j.cnki.stbccxb.2012.06.013

[17] Deng, Y., Huang, S., Laird, A. D., et al. (2019). Adsorption behaviour and mechanisms of cadmium and nickel on rice straw biochars in single- and binary-metal systems. Chemosphere, 218, 308–318. https://doi.org/10.1016/j.chemosphere.2018.11.081

[18] Li, L., Lu, Y. C., Liu, Y., et al. (2012). Adsorption mechanism of Cd(II) on corn straw biochar. Journal of Agro-Environment Science, 31(11), 2277–2283.

[19] Muhammad, R., Shafaqat, A., Farooq, M. Q., et al. (2016). Mechanisms of biochar mediated alleviation of toxicity of trace elements in plants: A critical review. Environmental Science and Pollution Research International, 23(3), 2230–2248. https://doi.org/10.1007/s11356-015-5697-7

[20] Fellet, G., Marmiroli, M., & Marchiol, L. (2014). Elements uptake by metal accumulator species grown on mine tailings amended with three types of biochar. Science of the Total Environment, 468–469, 598–608. https://doi.org/10.1016/j.scitotenv.2013.08.072

[21] Ji, H. Y., Wang, Y. Y., Liu, Y. X., et al. (2018). Research progress on preparation and application of biochar and modified biochar. Journal of Nuclear Agricultural Sciences, 32(11), 2281–2287.

[22] Wibowo, N., Setyadhi, L., Wibowo, D., et al. (2007). Adsorption of benzene and toluene from aqueous solutions onto activated carbon and its acid and heat treated forms: Influence of surface chemistry on adsorption. Journal of Hazardous Materials, 146(1–2), 237–242.

[23] Shen, Y., & Zhang, N. (2019). Facile synthesis of porous carbons from silica-rich rice husk char for volatile organic compounds (VOCs) sorption. Bioresource Technology, 282, 294–300. https://doi.org/10.1016/j.biortech.2019.03.025

[24] Zhu, S. H., Zhao, J. J., Yin, Y. J., et al. (2019). Adsorption of arsenic by goethite-modified biochar. Environmental Science, 40(06), 2773–2782. https://doi.org/10.13227/j.hjkx.201809191

[25] Shen, T., Zhao, K., Yan, Y. Y., et al. (2024). Bibliometric analysis of biochar application in heavy metal pollution. Hunan Agricultural Sciences, (10), 104–110.

[26] Mao, J. X., Xiang, P., Ma, H. Y., et al. (2023). Process mechanisms and influencing factors of heavy metal adsorption/passivation by straw biochar in soil. Asian Journal of Ecotoxicology, 18(5), 13–30.

[27] Feng, D., Liu, J. J., Ma, W. D., et al. (2024). Research progress on machine learning-based modeling of heavy metal adsorption by biochar. Industrial Water Treatment, 44(12), 1–11.

[28] Liang, K., Zhu, X. C., Wu, R. J., et al. (2025). Amelioration of red soil acidity by biochar: A meta-analysis. Soils, 57(6), 1387–1396.

[29] Li, D. L., & Wu, X. F. (2023). Common problems and case analysis of literature in meta-analysis papers. Acta Editologica, 35(5), 527–530.

[30] Liu, Y., Gao, Y., Zuo, Y. T., et al. (2025). Synergistic inhibition of Pb accumulation in pakchoi by biochar and microorganisms based on meta-analysis. Green Technology, 27(24), 78–84.

[31] Liu, H., Chen, C., Li, X., et al. (2024). Meta-analysis compares the effectiveness of modified biochar on cadmium availability. Frontiers in Environmental Science, 12, 1413047. https://doi.org/10.3389/fenvs.2024.1413047

[32] Mandal, J., Sharma, P. K., Mondal, D., et al. (2024). Meta-analysis of biochar as an amendment for arsenic mitigation in paddy soils. Current Pollution Reports, 10, 105–118. https://doi.org/10.1007/s40726-024-00374-y

Downloads

Published

04-08-2026

Issue

Section

Articles

How to Cite

Li, H., Gao, Y., Li, G., Chen, J., & Ji, J. (2026). A Meta-Analysis on the Effects of Modified Biochar Preparation and Structural Regulation on the Remediation of Soils Contaminated by Heavy Metals and Other Pollutants. International Journal of Natural Resources and Environmental Studies, 8(7), 1-21. https://doi.org/10.62051/ijnres.v8n7.01